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Atomic Foundations of Matter

Writing the formula

Aluminium has valency 3. Chlorine has valency 1. Swapped, they give AlCl₃.

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The rule

A symbol is an element's short name, such as Al. A count is a small number, such as the 3 in AlCl₃. To cut down is to divide both counts by the same number.

Swap the two valencies for counts. Cut the counts down by their shared factor. This gives the simplest formula. Write the symbols, and leave out a count of one.

Crossing the numbers is the same as swapping them.

Aluminium (valency 3) and chlorine (valency 1), side by side.
Step 1 of 3
  1. Aluminium (valency 3) and chlorine (valency 1), side by side.
  2. Cross the numbers: 3 becomes chlorine's count, 1 becomes aluminium's.
  3. Counts 1 and 3 share no factor. Write AlCl₃.

Swap, cut down, write

Swap the valencies, cut down, and write the formula
ElementsValenciesSwappedCut downFormula
Aluminium, chlorine3, 11, 31, 3AlCl₃
Potassium, oxygen1, 22, 12, 1K₂O
Calcium, oxygen2, 22, 21, 1CaO
Nitrogen, hydrogen3, 11, 31, 3NH₃

Calcium and oxygen swap to 2 and 2. Both share the factor 2. Divide each by 2 to get 1 and 1. A count of 1 is not written. So the formula is CaO.

Check the answer. One aluminium carries 1 × 3 = 3 hooks. Three chlorine carry 3 × 1 = 3 hooks. Both totals are 3. So every hook is used, and AlCl₃ is right.

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This track

  1. 0 Start here
  2. 1 Nothing is lost
  3. 2 Always the same proportion
  4. 3 Why those two hold
  5. 4 Weighing something you cannot see
  6. 5 Molecular mass
  7. 6 When it is not molecules
  8. 7 Valency
  9. 8 Writing the formula
  10. 9 The big picture
  11. 10 Track quiz

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